Solvent-free Synthesis of Nitriles from Aldehydes Catalyzed by KF/Al2O3, Montmorillonite KSF and K10

synthesis of sulfides from alcohols and thiols in solvent-freeconditions and deoxygenation of sulfoxides

کاتالیست یک سنتز جدید برای تیواترها توصیف شده است. واکنش الکل ها با آریل، هتروآریل و آلکیل تیو ل ها درحضور 1،3،5- تری آزو- 2،4،6- تری فسفرین-2،2،4،4،6،6 هگزاکلراید ((tapc به عنوان یک کاتالیست موُثر، بازده های خوب تا عالی از تیواترها را حاصل می کند. علاوه براین، واکنش تحت شرایط بدون فلز و بدون حلال پیش می رود، بنابراین یک مکمل جالب برای روش های شناخته شده سنتز تیواترها ارائه می دهد. یک مکانیسم ا...

Montmorillonite Ksf Catalyzed Facile Synthesis of Novel Spiro Heterocycles under Microwave Irradiation

The arylidienes of spiro thiazolidines (5) containing α,β-unsaturated function have been used as component of Micheal addition with equimolar amount of 2-aminopyridine (6a) to give novel spiro [indole-3,2′-pyrido[1,2-a]thiazolo[5,4-e]pyrimidines] (7) in a single step under microwaves in presence of montmorillonite KSF as solid support. The new improved synthetic method for spiro [indole-3, 2′-t...

CuCl2 Catalyzed Solvent-free One Pot Synthesis of Dihydropyrimidinones

Chemoselective Synthesis of Pentaerythritol Diacetals Catalyzed by CuO-CeO2 Nanocomposite under Solvent-free Conditions

CuO-CeO2 nanocomposite is reported as a green recyclable catalyst for the chemoselective synthesis of pentaerythritol diacetals from aromatic aldehydes under solvent-free conditions. The catalyst was synthesized by co-precipitation method and characterized by XRD, BET specific surface area, FESEM and EDS analysis. This procedure provides some advantages such as simple work-up, clean procedure, ...

Synthesis of electron-poor N-Vinylimidazole derivatives catalyzed by Silica nanoparticles under solvent-free conditions

Protonation of the highly reactive 1:1 intermediates, produced in the reaction between triphenylphosphine and acetylenic esters, by NH-acids such as azathioprine, imidazole or theophylline leads to the formation of vinyltriphenylphosphonium salts, which undergo a Michael addition reaction with a conjugate base to produce phosphorus ylides. Silica nanoparticles (silica NPs were prepared by therm...